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Beilstein J. Org. Chem. 2015, 11, 2747–2762, doi:10.3762/bjoc.11.296
Graphical Abstract
Scheme 1: Synthesis of homopolymers containing ferrocenyl and tetraethylene glycol groups.
Scheme 2: Synthesis of redox-robust triazolylbiferrocenyl polymers 4.
Scheme 3: Synthesis of cobaltocenium-containing polymers by ROMP.
Scheme 4: Cobaltocenium-appending copolymers by the ROMP approach (X = PF6, Y = BPh4 or Cl).
Scheme 5: Cobalt-containing polymers by click and ROMP approach.
Scheme 6: Synthesis of new cobalt-integrating block copolymers.
Scheme 7: Two alternative routes for the synthesis of redox-active cobalticenium-tethered polyelectrolytes.
Scheme 8: Oxanorbornene monomers for the synthesis of Ru-containing polymers by ROMP.
Scheme 9: ROMP synthesis of Ru-containing homopolymers.
Scheme 10: Synthesis of diblock copolymers incorporating ruthenium.
Scheme 11: Synthesis of Ru triblock copolymers.
Scheme 12: Synthesis of cross-linked Ru-containing triblock copolymers.
Scheme 13: Synthesis of Ir-containing homopolymers by ROMP.
Scheme 14: Monomers for Ir- and Os-containing ROMP polymers.
Scheme 15: ROMP block copolymers integrating Ir in their side chains.
Scheme 16: Synthesis of Rh-containing block copolymers.
Scheme 17: Access to rhodocenium-containing metallopolymers by ROMP.
Scheme 18: Synthesis of homopolymers equipped with Cu coordination centers.
Scheme 19: Synthesis of Cu-containing copolymers (spacer = –(CH2)5–; >C=O).
Scheme 20: Synthesis of polynorbornene bearing a polyoxometalate (POM) cluster in the side chain.
Scheme 21: Synthesis of Eu-containing copolymers by a ROMP-based route.